A double-stranded 1D-coordination polymer assembled using the tetravergent ligand 1,1 '-bis(4,2 ':6 ',4 ''-terpyridin-4 '-yl)ferrocene

作者：Klein Y Maximilian; Prescimone Alessandro; Constable Edwin C; Housecroft Catherine E^*

来源：Inorganic Chemistry Communications, 2016, 70: 118-120.

DOI：10.1016/j.inoche.2016.05.027

• X-ray
• 1D-coordination polymer
• Zinc
• Ferrocene
• Double-stranded chain

1,1'-Bis(4,2':6',4"-terpyridin-4'-yl)ferrocene (1) reacts with ZnCl2 to yield a double-stranded 1D-coordination polymer [{Zn-2(1)Cl-4}center dot CHCl3](n). The 1,1'-functionalized ferrocene core adopts a cisoid-conformation, giving rise to a folded conformation for 1 and a double-stranded 1D-polymer chain. This contrasts with previously reported multi-stranded chains supported by 4,2':6',4"-terpyridine ligands in which the multiple-nature of the chain arises from multinudear metal nodes.

• 出版日期2016-8