Nanosized high voltage cathode material LiMg0.05Ni0.45Mn1.5O4: Structural, electrochemical and in situ investigation

作者：Lafont U^*; Locati C; Borghols W J H; Lasinska A; Dygas J; Chadwick A V; Kelder E M

来源：Journal of Power Sources, 2009, 189(1): 179-184.

DOI：10.1016/j.jpowsour.2008.09.121

• High voltage spinel
• In situ XANES
• Li-ion battery
• Nanomaterials
• LiNi0.5Mn1.5O4

In this study a modified solid state synthesis (auto-ignition method) is used to form nanosized spinet type material LiMg0.05Ni0.45Mn1.5O4. This material presents a high voltage plateau at 4.75V vs. Li/Li+, Structural and electrochemical characterisations have been performed using a wide range of techniques (TEM, neutron diffraction, galvanostatic measurements, and impedance spectroscopy). Besides, in situ XAS has been performed to monitor the evolution of Ni and Mn oxidation state during Li intercalation. The material presents an ordered cubic spinet structure, good capacity retention upon cycling (131 mAh g(-1) at C/10 and 117 mAh g(-1) at 1C) and good electronic conductivity (10(-6) Scm(-1) at RT). The simultaneous presence of Mn3(+)/Mn4+ in the structure has been investigated and explained by inclusion of disordered nanodomains in the structure.

• 出版日期2009-4-1