Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

作者：Klopsch Isabel; Finger Markus; Wuertele Christian; Milde Bastian; Werz Daniel B; Schneider Sven^*

来源：Journal of the American Chemical Society, 2014, 136(19): 6881-6883.

DOI：10.1021/ja502759d

[ReCl3(PPh3)(2)(NCMe)] reacts with pincer ligand HN(CH2CH2PtBu2)(2) (HPNP) to five coordinate rhenium(III) complex [ReCl2(PNP)]. This compound cleaves N-2 upon reduction to give rhenium(V) nitride [Re(N)Cl(PNP)], as the first example in the coordination sphere of Re. Functionalization of the nitride ligand derived from N-2 is demonstrated by selective C N bond formation with MeOTf.

• 出版日期2014-5-14