A new diketopyrrolopyrrole-based co-polymer for ambipolar field-effect transistors and solar cells

作者：Tandy Kristen; Dutta Gitish K; Zhang Yuliang; Venkatramaiah N; Aljada Muhsen; Burn Paul L; Meredith Paul; Namdas Ebinazar B^*; Patil Satish

来源：Organic Electronics, 2012, 13(10): 1981-1988.

DOI：10.1016/j.orgel.2012.05.046

• Field-effect transistors
• Solar cells
• Donor-acceptor
• Semiconducting polymers
• Diketopyrrolopyrrole
• Ambipolar

A new thieno[3,2-b]thiophenediketopyrrolopyrrole-benzo[1,2-b:4,5-b%26apos;]dithiophene based narrow optical gap co-polymer (PTTDPP-BDT) has been synthesized and characterized for field-effect transistors and solar cells. In field-effect transistors the polymer exhibited ambipolar charge transport behaviour with maximum hole and electron mobilities of 10(-3) cm(2) V-1 s(-1) and 10(-5) cm(2)V(-1) s(-1), respectively. The respectable charge transporting properties of the polymer were consistent with X-ray diffraction measurements that showed close molecular packing in the solid state. The difference in hole and electron mobilities was explained by density functional theory calculations, which showed that the highest occupied molecular orbital was delocalized along the polymer backbone with the lowest unoccupied molecular orbital localized on the bis(thieno[3,2-b]thiophene)diketopyrrolopyrrole units. Bulk heterojunction photovoltaic devices with the fullerene acceptor PC70BM were fabricated and delivered a maximum conversion efficiency of 3.3% under AM1.5G illumination.

• 出版日期2012-10