Mild aerobic oxidation of alcohols catalysed by Fe2(SO4)3/4-OH-TEMPO/NaNO2

作者：Shi, Xiang-Jun; Qian, Jie; Tan, Fan-Fan; Yu, Chuan-Ming^*

来源：Journal of Chemical Research, 2013, 37(7): 398-401.

DOI：10.3184/174751913X13700197900636

• alcohols
• TEMPO
• iron salts
• aerobic oxidation
• oxygen

An environmentally friendly catalytic system of Fe-2(SO4)(3)/4-OH-TEMPO/NaNO2 has been developed for aerobic oxidation of alcohols to aldehydes and ketones. The catalytic system allowed efficient and selective oxidation of a wide range of alcohols using oxygen at 1 atmospheric pressure and room temperature. 100% selectivity and excellent conversion rates were observed for benzylic alcohols and cinnamyl alcohol.

• 出版日期2013-7
• 单位浙江工业大学