A simple Ag(I)-enyne cation

作者:Sanguramath Rajashekharayya A; Townsend Nell S; Russell Christopher A*
来源:Journal of Organometallic Chemistry, 2016, 811: 26-28.
DOI:10.1016/j.jorganchem.2016.03.009

摘要

A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 degrees C.

  • 出版日期2016-6-1

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