Upconversion Luminescence of Graphene Oxide through Hybrid Waveguide

作者:Li, Zongbao; Yang, Jianxin; Shi, Meng; Yang, Liu; Cheng, Yupeng; Hu, Xiaowen; Jiang, Xiaofang; Xing, Xiaobo*; He, Sailing*
来源:Journal of Physical Chemistry C, 2018, 122(29): 16866-16871.
DOI:10.1021/acs.jpcc.8b00962

摘要

Phonon-assisted upconversion is a promising way to generate short-wavelength emissions under excitation of long wavelength based on unique anti-Stokes luminescence properties. Graphene oxide nanosheets (GONs) exhibit excellent optical properties owing to quantum confinement and edge effects, which have driven research into fundamental principles and potential applications. Here, we experimentally demonstrate upconversion emission by exciting an easily fabricated GON hybrid waveguide (GHVV) with enhanced photothermal effects. The results reveal different origins of short-wavelength range and long-wavelength range in the upconversion spectra, whereas the emissive surface defects of GONs and GHW structure play significant roles in the behavior of photoluminescence. Introducing other upconversion materials to promote emission efficiency, the hybrid waveguide system might readily provide the possibility for the construction of upconversion fiber lasers and remote control of the upconversion luminescence.