Densimetric and ultrasonic characterization of pentaerythritol in water and in aqueous NaCl and MgCl2 solutions at different temperatures

作者：Krakowiak Joanna^*

来源：Journal of Chemical Thermodynamics, 2012, 54: 444-452.

DOI：10.1016/j.jct.2012.05.033

• Density
• Sound velocity
• Apparent molar volume
• Apparent molar isentropic compressibility
• Pentaerythritol
• Salts

The densities at T = (293.15, 298.15, 303.15, 308.15, 310.15, and 313.15) K and sound velocities at T = (298.15 and 310.15) K have been measured for pentaerythritol in pure water and in (1, 5, and 10) wt% aqueous solutions of sodium and magnesium chloride. From these data apparent molar volumes, V-Phi, and the apparent molar isenotropic compressibilities, K-S,K-Phi, of the polyol have been determined. The limiting apparent molar quantities and corresponding transfer parameters were also obtained and discussed in terms of various solute-solvent and solute-cosolute interactions.

• 出版日期2012-11