A new 3D Keggin-POM based metal-organic framework of Cu and H(2)biim: Assembly and properties of fluorescence and electrochemistry

作者：Shi, Zhenyu; Peng, Jun^*; Yu, Xia; Shen, Yan; Zhang, Zheyu; Alimaje, Kundawlet; Wang, Xiang

来源：Inorganic Chemistry Communications, 2013, 28: 85-89.

DOI：10.1016/j.inoche.2012.10.040

• Keggin
• Metal-organic framework
• Hydrothermal synthesis
• Electrochemical property

A new 3D Keggin-based metal-organic framework consisting of two kinds of Cu-H(2)biim chains, Cu-10(H-2-biim)(10)(PW12O40)(2)(OH)(4)center dot 5H(2)O 1 (H(2)biim=2,2'-biimidazole), has been synthesized under hydrothermal conditions. The TGA and PXRD measurements show that the framework is stable after removal of the guest water molecules. In addition, the luminescent and electrochemical properties of 1 have also been investigated.

• 出版日期2013-2
• 单位东北师范大学; 兴义民族师范学院