A seven-component metallosupramolecular quadrilateral with four different orthogonal complexation vertices

作者:Mittal Nikita; Saha Manik Lal; Schmittel Michael*
来源:Chemical communications, 2015, 51(85): 15514-15517.
DOI:10.1039/c5cc06324h

摘要

The 4-fold completive self-sorting of a ten-component library (7 dissimilar donors and 3 different acceptors) resulted in the clean self-assembly of four dynamic orthogonal complexes although >= 143 combinations are conceivable. Due to the non-interference of the complexes, each ligand of the four combinations was embedded to one side of the quadrilateral to serve as a linkage at one metal cornerstone. Finally, an integrative self-sorting of seven components generated the fully irregular scalene quadrilateral QL1.

  • 出版日期2015