A kinetic study of the strontium extraction by metallothermic reduction using submerged SrO powders injection

作者：Muniz R^*; Flores A; Torres J; Luna S; Rodriguez N

来源：Materials Letters, 2008, 62(4-5): 637-640.

DOI：10.1016/j.matlet.2007.06.024

• strontium recovery
• submerged powder injection
• metallothermic reduction
• reaction kinetic

This work reports the results of laboratory experiments conduced to follow the kinetics of strontium recovery into the Al-Mg alloy by metallothermic reduction of SrO. The reagent was incorporated to molten alloy by the use of submerged powders injection technique. The variables analyzed were the injection time, the melt temperature and the initial magnesium content. Magnesium is added to the melt to increase the reactivity and reduce the surface tension of the molten aluminum. It was possible to increase the strontium content from 0 to 5 wt.% after 60 min of treatment. The results were fitted to a general kinetic equation, which allowed it to obtain the kinetic parameters, i.e. order of reaction and activation energy of the process. As the main mechanism of the strontium recovery process is of diffusive type, the global process rate increases as the temperature and initial amount of the magnesium increased.

• 出版日期2008-2-29