A modified Ortega method to evaluate the activation energies of solid state reactions

作者：Han Yunqing; Li Tianxiang; Saito Kozo^*

来源：Journal of Thermal Analysis and Calorimetry, 2013, 112(2): 683-687.

DOI：10.1007/s10973-012-2591-0

• Isoconversional method
• Average integral method
• Activation energy
• Kinetic analysis

The application of the average linear integral isoconversional method developed by Ortega for evaluating the activation energies of solid state reactions may be hindered by experimental noise and the uncertainties associated with selecting appropriate reaction segments. This paper suggests a procedure, called the modified Ortega method, which can avoid or minimize these hindrances. By applying the modified Ortega method to the kinetic analyses of both simulated and experimental data, a more consistent dependence of the activation energy on the extent of reaction conversion was found with those calculated from the modified Vyazovkin method and the Friedman method.

• 出版日期2013-5