Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations

作者:Dayaker Gandrath; Sreeshailam Aare; Chevallier Floris; Roisnel Thierry; Krishna Palakodety Radha*; Mongin Florence
来源:Chemical communications, 2010, 46(16): 2862-2864.
DOI:10.1039/b924939g

摘要

A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.

  • 出版日期2010