科研之友
微信
新浪微博
Facebook
分享链接
摘要
A simple and green flow injection chemiluminescence (FI-CL) method for determination of the fungicide azoxystrobin was described for the first time. CL signal was generated when azoxystrobin was injected into a mixed stream of luminol and KMnO4. The CL signal of azoxystrobin could be greatly improved when an off-line ultrasonic treatment was adopted. Meanwhile, the signal intensity increases with the analyte concentration proportionally. Several variables, such as the ultrasonic parameters, flow rate of reagents, concentrations of sodium hydroxide solution and CL reagents (potassium permanganate, luminol) were investigated, and the optimal CL conditions were obtained. Under optimal conditions, the linear range of 1-100ng/mL for azoxystrobin was obtained and the detection limit (3 sigma) was determined as 0.13ng/mL. The relative standard deviation was 1.5% for 10 consecutive measurements of 20ng/mL azoxystrobin. The method has been applied to the determination of azoxystrobin residues in water samples.
- 出版日期2013-9
- 单位安徽工业大学
