Non-classical heteroacenes: synthesis and properties of anthra[2,3-c:6,7-c ']dithiophene derivatives

作者:Djukic Brandon; Perepichka Dmitrii F*
来源:Chemical Communications, 2011, 47(47): 12619-12621.
DOI:10.1039/c1cc15623c

摘要

A new class of linear heteroacenes, anthra[2,3-c:6,7-c']dithiophenes, containing non-classical (non-Kekule ) thiophene in a 22-electron pi-conjugated system have been prepared by electrochemical reduction. The electronic properties have been studied by DFT calculations and spectroelectrochemistry, supporting the formation of a triplet electronic structure.

  • 出版日期2011