Aryl 5-substitution of a phenyl-pyridine based ligand as a viable way to influence the opto-electronic properties of bis-cyclometalated Ir(III) heteroleptic complexes

作者：Grisorio Roberto; Suranna Gian Paolo^*; Mastrorilli Piero; Mazzeo Marco; Colella Silvia; Carallo Sonia; Gigli Giuseppe

来源：Dalton Transactions, 2013, 42(24): 8939-8950.

DOI：10.1039/c3dt50576f

This manuscript reports on the synthesis, the photophysical study and the electroluminescent properties of a series of heteroleptic cyclometalated iridium(III) complexes based on 2,5-diaryl-pyridines as (CN)-N-boolean AND cyclometalating ligands and acetylacetonate as ancillary ligand. The complexes were characterised by elemental analysis, ESI-MS, multinuclear NMR, TGA and electrochemistry. Their optical properties were investigated by UV-Vis and photoluminescence. DFT and TD-DFT calculations provided further insights into the effects of the 5-aryl substitution on the electronic and photophysical properties of the new complexes. The presence of suitable pi-extended ligands exerts a beneficial effect on the performances of the corresponding solution-processed light-emitting diodes, leading to a maximum brightness of 10 620 cd m(-2) at a current efficiency of 10.0 cd A(-1).

• 出版日期2013