科研之友
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摘要
The selective synthesis of a photoluminiscent macrocycle containing germanium atoms in conjugation with two aromatic segments has been accomplished by ruthenium-based olefin metathesis. The macrocycle shows blue emission with 40% quantum efficiency. The optical properties are interpreted with the help of theoretical DFT calculations using B3LYP/6-31G** and B3LYP/Lan12dz with a remarkable match between the measured and the calculated absorption characteristics.
- 出版日期2010-9
