Multifunctional red phosphorescent bis-cyclometallated iridium complexes based on 2-phenyl-1,2,3-benzotriazole ligand and carbazolyl moieties

作者：Malinauskas Tadas; Daskeviciene Maryte; Kazlauskas Karolis^*; Su Hai Ching; Grazulevicius Juozas Vidas; Jursenas Saulius; Wu Chung Chih; Getautis Vytautas

来源：Tetrahedron, 2011, 67(10): 1852-1861.

DOI：10.1016/j.tet.2011.01.026

• Carbazole
• Iridium complex
• Phosphorescence
• Triazole

Multifunctional phosphorescent bis-cyclometallated iridium(III) complexes based on the 2-phenyl-1,2,3-benzotriazole moiety and bearing branched hole-transporting carbazole fragments were synthesized. The isolated compounds were found to be amorphous and expressed very good solubility. Introduction of flexible aliphatic chains of various lengths into the iridium complexes enabled manipulation of their glass transition temperature. The iridium complexes exhibited red phosphorescence emission at 650 nm with the lifetime of 5.7 mu s and phosphorescence quantum yields of 0.22 and 0.17 in solution and solid state, respectively, at room temperature. The shielding effect of the carbazolyl moieties on the concentration quenching of phosphorescence of the iridium centers was found to result in the increased excited state lifetime and quantum yield due to the suppressed exciton migration. Non-optimized OLED devices, based on the phosphorescent bis-cyclometallated iridium(III) complex without host material were fabricated and their electroluminescence properties were evaluated.

• 出版日期2011-3-11
• 单位中国科学院电工研究所