A new 1,2,3,4-tetrahydroquinoxaline derivative combining baicalein and 1,2-diphenylethylenediamine moieties: Structure and its fluorescence-based detection of nitroaromatics

作者：Fu, Qiang; Zhang, Yao; Liu, Baokai; Guo, Fang^*

来源：Journal of Molecular Structure, 2018, 1171: 69-75.

DOI：10.1016/j.molstruc.2018.05.089

• 1,2,3,4-tetrahydroquinoxaline derivative
• Baicalein
• 1,2-diphenylethylenediamine
• Fluorescence detection

A new heterocyclic 1,2,3,4-tetrahydroquinoxaline derivative compound, named as (2R,3R)-5-hydroxy2,3,8-tripheny1-3,4-dihydro-1H-pyrano[3,2-f]quinoxalin-10(2H)-one (A) has been obtanied from baicalein and 1,2,3,4-tetrahydroquinoxaline through a new and relatively straightforward crystallization approach. The compound A has been characterialzed by IR, H-1 NMR, TGA and X-ray crystallography. The compound shows good photolumicent property and the ability to detect trace amounts of nitrobenzene, 2-nitrotoluene and 3-nitrotoluene.

• 出版日期2018-11-5
• 单位辽宁大学