Unusual Aryl Migration in a Mesmeric Betaine in the Solid and Liquid State: Mechanistic Insights into the SNAr Reaction

作者：Cantillo David^*; Avalos Martin; Babiano Reyes; Cintas Pedro; Jimenez Jose L; Light Mark E; Palacios Juan C

来源：Journal of Organic Chemistry, 2010, 75(12): 4300-4303.

DOI：10.1021/jo100350t

An intramolecular SNAr mechanism has been identified in the unexpected aryl migration observed in a mesomeric betaine. The process changes drastically the optical and spectroscopic properties and should be a valuable model for related heteroaromatic systems.

• 出版日期2010-6-18