A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

作者:Evans Nicholas H; Serpell Christopher J; Beer Paul D*
来源:New Journal of Chemistry, 2011, 35(10): 2047-2053.
DOI:10.1039/c1nj20109c

摘要

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1:1 CDCl(3):CD(3)OD.

  • 出版日期2011