Asymmetric supercapacitors based on carbon nanofibre and polypyrrole/nanocellulose composite electrodes

作者：Tammela, Petter; Wang, Zhaohui; Frykstrand, Sara; Zhang, Peng; Sintorn, Ida-Maria; Nyholm, Leif; Stromme, Maria^*

来源：RSC Advances, 2015, 5(21): 16405-16413.

DOI：10.1039/c4ra15894f

• ENERGY-STORAGE DEVICES
• POLYMER-PENDANT INTERACTIONS
• CONTAINING FUNCTIONAL-GROUPS
• ELECTROCHEMICAL CAPACITORS
• CONDUCTING POLYMERS
• ACTIVATED CARBON
• POLYPYRROLE
• CELLULOSE
• PAPER
• PERFORMANCE

Asymmetric, all-organic supercapacitors (containing an aqueous electrolyte), exhibiting a capacitance of 25 F g(-1) (or 2.3 F cm(-2)) at a current density of 20 mA cm(-2) and a maximum cell voltage of 1.6 V, are presented. The devices contain a composite consisting of polypyrrole covered Cladophora cellulose fibres (PPy-cellulose) as the positive electrode while a carbon nanofibre material, obtained by heat treatment of the same PPy-cellulose composite under nitrogen gas flow, serves as the negative electrode. Scanning and transmission electron microscopy combined with X-ray photoelectron spectroscopy data show that the heat treatment gives rise to a porous carbon nanofibre material, topologically almost identical to the original PPy-cellulose composite. The specific gravimetric capacitances of the carbon and the PPycellulose electrodes were found to be 59 and 146 F g(-1), respectively, while the asymmetric supercapacitors exhibited a gravimetric energy density of 33 J g(-1). The latter value is about two times higher than the energy densities obtainable for a symmetric PPy-cellulose device as a result of the larger cell voltage range accessible. The capacitance obtained for the asymmetric devices at a current density of 156 mA cm(-2) was 11 F g(-1) and cycling stability results further indicate that the capacity loss was about 23% during 1000 cycles employing a current density of 20 mA cm(-2). The present results represent a significant step forward towards the realization of all-organic material based supercapacitors with aqueous electrolytes and commercially viable capacitances and energy densities.

• 出版日期2015