Microconcave MAPbBr3 Single Crystal for High-Performance Photodetector

作者：Liu, Han; Wei, Xiangfeng; Zhang, Zhixiang; Lei, Xunyong; Xu, Wenchao; Luo, Linbao; Zeng, Hualing; Lu, Ruifeng; Liu, Jiehua^*

来源：Journal of Physical Chemistry Letters, 2019, 10(4): 786-792.

DOI：10.1021/acs.jpclett.9b00038

• HALIDE PEROVSKITES
• CH3NH3PBX3 X
• LOW-COST
• GROWTH
• EMERGENCE
• LENGTHS
• WAFERS

We present the first report of a new suspension method for obtaining cubic MAPbBr(3) single crystal with a concave surface. The cubic MAPbBr(3) crystal with microconcavity possesses good crystallinity and carrier lifetime. Excellent photoelectric performance was provided by the concavity-based MAPbBr(3) photodetectors because of the good light trapping and shortened carrier pathway. As a result, the concavity-based photodetector exhibits superior responsivity of 62.9 and 5.43 A W-1 and EQE of 1.50 X 10(4)% and 1.30 X 10(3)% under low-power and high-power 520 nm irradiation of 3.67 mu W cm(-2) and 35.4 mW cm(-2) at 3 V, respectively, which are more than 500% higher than those of the plane-based photodetector. In particular, the concavity-based photodetector has an ultrahigh detectivity of 6.5 X 10(12) Jones at ultralow power of 3.67 mu W cm(-2), which is 6.5 times higher than that of the planar device.

• 出版日期2019-2-21
• 单位南京理工大学; 中国科学技术大学; 合肥工业大学