Novel Dihydropyrazines and their Double ortho-Annulation to Hexaazapentacenes

作者:Strathausen Rainer; Beckert Rainer*; Fleischhauer Jan; Mueller Dirk; Goerls Helmar
来源:Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2014, 69(5): 641-649.
DOI:10.5560/ZNB.2014-4002

摘要

The cycloacylation of oxalic amidines 7 with bis-imidoylchlorides 6 furnished the dihydropyrazine derivatives 8. Due to their vicinal amino-imino substructures, they provide good preconditions for a double intramolecular ring closure reaction. An alternative synthesis for hexaaza-pentacenes 1 was developed using potassium carbonate as the base and lead tetraacetate as the oxidizing agent.

  • 出版日期2014-5