A new dimeric polyoxotungstate based on the monovacant anion [SiW11O39] connected by a hexa-metal cluster (CeCs5)-Cs-III

作者：Chen Hongli; Wang Enbo^*; Ding Yan; Zhang Zhiming; Xu Xinxin; Wang Xinlong

来源：Journal of Coordination Chemistry, 2008, 61(1): 109-115.

DOI：10.1080/00958970701687093

• monovacant
• Keggin-type polyoxotungstates
• three-dimensional
• thermal stability

A new dimeric polyoxotungstate, based on the monovacant anion [SiW11O39] connected by a hexa-metal cluster (CeCs5)-Cs-III, is synthesized and characterized by single-crystal X-ray diffraction, IR, TG and electrochemistry. The polyoxoanions are connected to 3D structures by additional alkali metal ions.

• 出版日期2008
• 单位吉林工商学院; 东北师范大学