科研之友
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摘要
MCrAlY (M=Ni, Co) coatings are commonly used to protect the underlying superalloy component in industrial gas turbines and aeroengines from oxidation attack. They also function as bond coats for thermal barrier coatings (TBC). The chemical life time of the coated component is mainly governed by the depletion of the beta-phase in the bond coat as a result of simultaneously occurring surface oxidation and interdiffusion between the coating and the substrate. A new computational approach to model the microstructural evolution in MCrAlY (M=Ni, Co) coatings on Ni base superalloys was undertaken in the present study. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and wavelength dispersive X-ray spectroscopy (WDX) was employed to characterise MCrAlY coated superalloy samples after exposure at 1000 and 1100 degrees C. Phases were identified by electron backscatter diffraction (EBSD) and correlated with SEM/EDX/WDX analyses. Modelling of the microstructural evolution was carried out considering simultaneously occurring surface oxidation and interdiffusion processes. A flux based calculation of the concentration profiles and stable phases was performed, taking into account diffusion of all elements in the gamma, gamma ' and beta-NiAl phases. Good agreement was found between the observed and computed phase distributions after specific time intervals. The computed widths of the beta-depletion zones showed satisfactory agreement with the measurements. Additionally, the model was able to predict the formation of a TCP-phase and its penetration into the substrate with increasing exposure time in one of the investigated coating systems.
- 出版日期2015-1
