An efficient method to synthesize HMX by nitrolysis of DPT with N2O5 and a novel ionic liquid

作者：Zhi Hui Zhen; Luo Jun; Feng Guang An; Lv Chun Xu^*

来源：Chinese Chemical Letters, 2009, 20(4): 379-382.

DOI：10.1016/j.cclet.2008.12.040

• DPT
• Nitrolysis
• N2O5
• Acidic ionic liquid

A novel polyethylene glycol (PEG)-200-based dicationic acidic ionic liquid (PEG(200)-DAIL) was used to synthesize HMX from DPT by nitrolysis with N2O5. It was found that either N2O5 or PEG(200)-DAIL could improve the yield. Furthermore, the combined use of PEG(200)-DAIL and N2O5 could increase the yield of HMX to 64% with the used quantity of HNO3 decreased dramatically.

• 出版日期2009-4
• 单位南京理工大学