Facile synthesis of yellow-emitting CaAlSiN3:Ce3+ phosphors and the enhancement of red-component by co-doping Eu2+ ions

作者：Chen, Jingjing; Zhao, Yang; Li, Guanghao; Mao, Zhiyong^*; Wang, Dajian; Bie, Lijian^*

来源：Solid State Communications, 2017, 255: 1-4.

DOI：10.1016/j.ssc.2017.02.010

• Phosphor
• CaAlSiN3:Ce3+
• Atmospheric pressure synthesis
• Photoluminescent properties

In this paper, facile synthesis of CaAlSiN3: Ce3+ yellow-emitting phosphors under atmospheric pressure at a moderate temperature and their photoluminescent properties are reported. The prepared CaAlSiN3: Ce3+ phosphors exhibit a broad yellow emission band positioned at 580 nm and covering a bandwidth of 150 nm. The thermal stability of CaAlSiN3: Ce3+ phosphors shows obvious superiority than the commercial YAG: Ce3+ phosphor, indicating its promising application prospect in power LEDs. In addition, the enhancement of red-light component for CaAlSiN3: Ce3+ phosphor is demonstrated by co-doping Eu2+ ions. This study offers a facile route to prepare CaAlSiN3: Ce3+ yellow-emitting phosphors, which may be used as a promising candidate for high performance white LEDs.

• 出版日期2017-4
• 单位天津理工大学