A water-soluble metal-organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

作者：Sukul, Pradip K.; Bose, Purnandhu; Takei, Toshiaki; Yaghi, Omar M.; He, Ying; Lee, Myongsoo; Tashiro, Kentaro^*

来源：Chemical Communications, 2016, 52(8): 1579-1581.

DOI：10.1039/c5cc08973e

• NANOSTRUCTURES
• FABRICATION
• DESIGN

Water-soluble metal-organic complex array 1, bearing Ru(II), Pt(II) and Rh(III) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembly behaviours in aqueous media. NaClinduced aggregation of 1 at neutral pH was suppressed in phosphate buffered saline containing a mixture of Cl-, HPO42- and H2PO4-, which is unconventional for a peptide amphiphile.

• 出版日期2016
• 单位吉林大学