Dynamic modeling of electrical characteristics of solid oxide fuel cells using fractional derivatives

作者：Cao Hongliang; Deng Zhonghua^*; Li Xi; Yang Jie; Qin Yi

来源：International Journal of Hydrogen Energy, 2010, 35(4): 1749-1758.

DOI：10.1016/j.ijhydene.2009.11.103

• Solid oxide fuel cell
• Transient equivalent circuit
• Electrochemical impedance spectroscopy
• Integer order dynamic model
• Fractional order dynamic model

An efficient controller is greatly important for the quick load-following response of solid oxide fuel cell (SOFC) power systems, which is vital for the fuel utilization and the life of the stack. To design such a controller, an accurate dynamic model of SOFC electrical characteristics is critical. Here an integer order dynamic model is established by a transient equivalent circuit, and then a fractional order dynamic model is done in the perspective of the fractional derivatives theory. The parameters of the dynamic models then are optimized via genetic algorithms according to electrochemical impedance spectroscopy (EIS) experimental data. Finally, the dynamic response experiments from the models are studied. The results show that the fractional order dynamic model has higher accuracy for representing the dynamics of the SOFC electrical characteristics, which lays a solid foundation for the controller based on the accurate model.

• 出版日期2010-2
• 单位华中科技大学; 中国地质大学（北京）