A chiral mononuclear Dy-III complex with field-induced single molecule magnet behavior

作者：Peng, Guo^*; Zhang, Ying-Ying; Li, Zhao-Yang

来源：Inorganic Chemistry Communications, 2017, 85: 66-69.

DOI：10.1016/j.inoche.2017.06.017

• Chirality
• Single molecule magnet
• Pyridine-N-oxide

A chiral mononuclear Dy-III complex, formulated [Dy(PNO)(6)(H2O)(2)]Cl-3 (1) (PNO = pyridine-N-oxide), has been prepared by using an achiral ligand through spontaneous resolution. Structure analyses show that complex 1 consists of a Dy-III mononuclear unit and such units interact with each other by hydrogen bonds to form helical chains along a axis. The crystals of 1 are optically active and opposite Cotton effects can be observed in the circular dichroism (CD) spectra. Magnetic, studies reveal that complex 1 exhibits field-induced single molecule magnet behavior with an energy hairier of 49 K.

• 出版日期2017-11
• 单位南京理工大学