Ag films with enhanced adhesion fabricated by solution process for solar reflector applications

作者:Chen, Dexin; Zhang, Yan; Bessho, Takeshi; Kudo, Takahiro; Sang, Jing; Hirahara, Hidetoshi; Mori, Kunio; Kang, Zhixin*
来源:Solar Energy Materials and Solar Cells, 2016, 151: 154-161.
DOI:10.1016/j.solmat.2016.03.010

摘要

simple and inexpensive solution process has been developed to construct a silver film with enhanced adhesion by electroless plating for solar reflector applications. X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), atomic force microscopy (AFM) and field emission scanning electron microscopy (FE-SEM) were employed to characterize the surfaces. This reinforced adhesion is due to chemical covalent bonds between silver and substrate atoms. Silver maintains its unique conductivity even as a film on the ABS surface as demonstrated by four-point probe measurement. Moreover, UV/VIS/NIR spectrometer data confirms high reflectance of the Ag films in the infrared region indicating potential application for solar coatings. The method presented a convenient, compatible, and easily scalable manufacturing process with higher efficiency, which is of significant value for industrial fabrication of silver films and could have a promising future in concentrating solar systems.