Nd/Dy Resolution by SPE-Based Elution Chromatography with Bis(2-ethylhexyl) Phosphate (HDEHP) -Impregnated Fiber-Packed Bed

作者:Sasaki Taka aki*; Uchiyama Shoichiro; Fujiwara Kunio; Sugo Takanobu; Umeno Daisuke; Saito Kyoichi
来源:Kagaku Kogaku Ronbunshu, 2015, 41(4): 220-227.
DOI:10.1252/kakoronbunshu.41.220

摘要

Bis(2-ethylhexyl) phosphate (IIDEHP) as an acidic extractant was impregnated onto a polymer chain grafted onto a 6-nylon fiber at a density of 0.43 mollkg-product. Neodymium and dysprosium ions loaded onto the fiber packed into a bed were separated by elution chromatography using 0.2, 0.3, and 1.534 hydrochloric acid as an eluent. At various space velocities and loaded amounts, the HDEHP-impregnated fiber-packed bed exhibited a higher peak height and a narrower half width because of shorter dilfusional mass-transfer path of ions and larger external area per volume. The leakage of HDEHP impregnated was found to be negligible.

  • 出版日期2015