A metal-organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules

作者：Hou, Chaoyi; Bai, Yue-Ling^*; Bao, Xiao Li; Xu, Liangzhen; Lin, Rong-Guang; Zhu, Shourong; Fang, Jianhui; Xu, Jiaqiang

来源：Dalton Transactions, 2015, 44(17): 7770-7773.

DOI：10.1039/c5dt00762c

• POROUS COORDINATION POLYMER
• CRYSTAL
• ADSORPTION
• TOPOLOGIES
• COMPLEX

A new porous metal-organic framework (MOF) {[Cu-4(OH)(2)(tci)(2)-(bpy)(2)]center dot 11H(2)O} (1) based on a tetranuclear copper cluster with intracluster antiferromagnetic interactions was synthesized. Quartz crystal microbalance (QCM) sensor studies reveal sensitive and selective sensing for small molecules.

• 出版日期2015
• 单位福建农林大学; 上海大学