A Highly Selective Ratiometric Chemosensor for Hg2+ Based on 1,2-Diaminoanthraquinone

作者:Kim Sung Hoon; Gwon Seon Young; Bae Jin Seok*
来源:Sen-I Gakkaishi, 2014, 70(10): 254-257.
DOI:10.2115/fiber.70.254

摘要

A highly selective colorimetric chemosensor for Hg2+ based on 1,2-diaminoanthraquinone was investigated. 1,2-Diaminoanthraquinone showed color change only with Hg2+, but it showed no significant changes upon addition of other metal ions such as Fe3+, Na+, mg(2+), pb(2+), cd(2+) Ni2+, Cu2+ and Zn2+. The solvatochromic responses of the 1,2diaminoanthraquinone in several solvents of widely different polarities were measured; positive solvatochromism, with a large bathochromic shift, was observed from toluene to DMSO.

  • 出版日期2014-10