Ni3Si2O5(OH)4 multi-walled nanotubes with tunable magnetic properties and their application as anode materials for lithium batteries

作者：Yang, Yan; Liang, Qingqin; Li, Jinghong; Zhuang, Yuan; He, Yunhua; Bai, Bo; Wang, Xun^*

来源：Nano Research, 2011, 4(9): 882-890.

DOI：10.1007/s12274-011-0144-7

• Silicate nanotubes
• Ni nanocrystals
• lithium battery
• magnetic properties

Highly crystalline and thermally stable pure multi-walled Ni3Si2O5(OH)(4) nanotubes with a layered structure have been synthesized in water at a relatively low temperature of 200-210 A degrees C using a facile and simple method. The nickel ions between the layers could be reduced in situ to form size-tunable Ni nanocrystals, which endowed these nanotubes with tunable magnetic properties. Additionally, when used as the anode material in a lithium ion battery, the layered structure of the Ni3Si2O5(OH)(4) nanotubes provided favorable transport kinetics for lithium ions and the discharge capacity reached 226.7 mA center dot h center dot g(-1) after 21 cycles at a rate of 20 mA center dot g(-1). Furthermore, after the nanotubes were calcined (600 A degrees C, 4 h) or reduced (180 A degrees C, 10 h), the corresponding discharge capacities increased to 277.2 mA center dot h center dot g(-1) and 308.5 mA center dot h center dot g(-1), respectively.

• 出版日期2011-9
• 单位长安大学; 清华大学