Diiodido(1,10-phenanthroline-kappa N-2,N ')platinum(II)

作者:Ha Kwang*
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66(1): M65-U705.
DOI:10.1107/S1600536809053100

摘要

In the title complex, [PtI2(C12H8N2)],the Pt2 ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar molecules, with a maximum deviation of 0.170 (3) angstrom from the least-squares plane, are stacked in columns along the c axis with a Pt center dot center dot center dot Pt distance of 4.8510 (6) angstrom. In the column, pi-pi interactions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.703 (5) angstrom.

  • 出版日期2010-1