Aromatic donor-acceptor interactions in non-polar environments

作者:Prentice Giles M; Pascu Sofia I; Filip Sorin V; West Kevin R; Pantos G Dan*
来源:Chemical communications, 2015, 51(39): 8265-8268.
DOI:10.1039/c5cc00507h

摘要

We have evaluated the strength of aromatic donor-acceptor interactions between dialkyl naphthalenediimide and dialkoxynaphthalene in non-polar environments. H-1 NMR, UV-vis spectroscopy and isothermal titration calorimetry were used to characterise this interaction. We concluded that the strength of donor-acceptor interactions in heptane is sufficient to drive supramolecular assemblies in this and other aliphatic solvents.

  • 出版日期2015