A one-pot synthesis of polysulfane-bearing block copolymer nanoparticles with tunable size and refractive index

作者：Lim Jeewoo; Cho Yunshik; Kang Eun Hye; Yang Sanghee; Pyun Jeffrey; Choi Tae Lim; Char Kookheon

来源：Chemical communications, 2016, 52(12): 2485-2488.

DOI：10.1039/c5cc08490c

A one-pot synthesis of sulfur-rich polymer nanoparticles through a ring-opening metathesis polymerization is reported. The nanoparticles are formed in situ from diblock copolymers containing a polynorbornene derivative bearing cyclic polysulfanes. The refractive indices of the resulting nanoparticles are readily controlled in the range from 1.54 to nearly 1.65.

• 出版日期2016