A Porous 4d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Physical Properties

作者：Liu Guang Xiang^*; Li Xin Long; Zha Xiao Chun; Zhang Chun You; Wang Yan; Ren Xiao Ming

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2011, 637(11): 1555-1559.

DOI：10.1002/zaac.201100141

• Heterometallic coordination polymer
• Porous materials
• Silver
• Lanthanum
• Gas adsorption

A 4d-4f heterometallic coordination polymer, [AgLa(pydc)(2)]center dot 3H(2)O (1) (H(2)pydc = pyridine-3,4-dicarboxylic acid), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a three-dimensional (3D) framework containing one-dimensional (1D) channels occupied by free water molecules, which is constructed from 1D inorganic heterometallic chains and linear pydc linkers. To the best of our knowledge, complex 1 represents a rare example of 3D open-framework 4d-4f heterometallic coordination polymer. Moreover, after removal of the water molecules from complex 1, the remaining material has high thermal stability and good adsorption behavior towards nitrogen gas.

• 出版日期2011-9
• 单位安庆师范大学