A fast redox-induced switching mechanism in a conformationally controllable molecular thread in solution

作者:Zazza Costantino*; Mancini Giordano; Amadei Andrea; Sanna Nico; Aschi Massimiliano
来源:Physical Chemistry Chemical Physics, 2010, 12(18): 4552-4554.
DOI:10.1039/b926627e

摘要

Irreversible redox-induced relaxation processes occurring in a synthetic thread for rotaxane-based molecular devices are investigated; the results show that such a system in solution allows chemists to efficiently realize a nanosecond timescale/electrochemically-driven "conformational shaping'' through simple control of non-covalent interactions.

  • 出版日期2010