Application of sulfonated carbon-based catalyst for the furfural production from D-xylose and xylan in a microwave-assisted biphasic reaction

作者：Wang Yantao; Delbecq Frederic; Kwapinski Witold; Len Christophe^*

来源：Molecular Catalysis, 2017, 438: 167-172.

DOI：10.1016/j.mcat.2017.05.031

• Furfural
• Biphasic system
• Heterogeneous catalyst
• Microwave-assisted dehydration
• Sulfonated char

Sulfonated carbon-based catalyst has been prepared, characterized by elemental analysis, SEM, EDX and FTIR and tested as a heterogeneous catalyst in the dehydration of D-xylose and xylan to produce furfural as target compound. With the use of the catalyst the appropriate reaction temperature and time in a mixture of water-CPME (1:3, v/v) were 190 degrees C and 60 min, in both cases. In these conditions, dehydration starting from D-xylose and xylan gave 60 and 42% of furfural yields, respectively. The influence of temperature, the residence time and the substrate to catalyst ratios on the D-xylose conversion and furfural selectivity were investigated.

• 出版日期2017-9