A chiral spin crossover metal-organic framework

作者：Liu, Wei; Bao, Xin; Mao, Ling Ling; Tucek, Jiri; Zboril, Radek; Liu, Jun Liang; Guo, Fu Sheng; Ni, Zhao Ping; Tong, Ming Liang^*

来源：Chemical communications, 2014, 50(31): 4059-4061.

DOI：10.1039/c3cc48935c

A chiral metal-organic framework exhibiting spin crossover (SCO) property, [Fe-II(mptpy)(2)]center dot EtOH center dot 0.2DMF (1 center dot solv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (T-c1 = 200 K) and above (T-c2 = 357 K) room temperature.

• 出版日期2014
• 单位南京理工大学; 中山大学