Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir

作者：Lee Haeri; Kim Eun Ji; Ahn Jungmin; Noh Tae Hwan; Jung Ok Sang^*

来源：Journal of Molecular Structure, 2012, 1010: 111-115.

DOI：10.1016/j.molstruc.2011.11.040

• Anion effects
• 2,3-Bis(picolinoyloxy)naphthalene
• Metallamacrocyclodimer
• Molecular storage
• Silver(I) complex

Ionic macrocyclodimeric silver(I) complexes, [Ag(L)](2)(X)(2) (L = 2,3-bis(picolinoyloxy)naphthalene; X- = PF6-, ClO4-, BF4-, and NO3-) were synthesized. Single crystals consisting of cationic 22-membered metallamacrocycles with four pyridyl groups and two naphthyl groups were proven to have inter-cyclodimeric cavity with aromatic walls suitable for storage of small molecules. The nature of polyatomic counteranions plays a significant role in storage of small molecules.

• 出版日期2012-2-29