Aquabis(1H-imidazole-kappa N-3)bis(4-methyl-benzoato)-kappa O;kappa O,O '-nickel(II)

作者：Song, Wen-Dong^*; Fan, Run-Zhen; Wu, Hong-Mian

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64(5): M648-U367.

DOI：10.1107/S1600536808009471

In the mononuclear title compound, [ Ni(C8H7O2)(2)(C3H4N2)(2)( H2O)], the Ni-II atom is coordinated by three carboxylate O atoms ( from a bidentate 4-methylbenzoate ligand and a monodentate 4-methylbenzoate ligand), two N atoms (from two imidazole ligands) and a water molecule in an octahedral geometry. Intermolecular O-H center dot center dot center dot O hydrogen-bonding interactions lead to infinite chains, which are further self-assembled into a supramolecular network through intermolecular N H center dot center dot center dot O hydrogen- bonding interactions and pi-pi stacking [centroid-centroid distance = 3.717 ( 2) angstrom].

• 出版日期2008-5
• 单位广东海洋大学