A bimetallic Co-II-Dy-III complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)(3)](4)[Co(H2O)(6)](2)center dot 6H(2)O}(n)

作者：Li, Jun-Xia^*; Du, Zhong-Xiang; Zhu, Bao-Lin; An, Hui-Qin; Dong, Jian-Xun; Hu, Xiao-Jing; Huang, Wei-Ping

来源：Inorganic Chemistry Communications, 2011, 14(4): 522-525.

DOI：10.1016/j.inoche.2011.01.012

• Oxydiacetic acid
• Cobalt-dysprosium polymer
• Fluorescence
• EPR
• Magnetic properties
• TGA

A novel 3d-4f heteronuclear coordination polymer containing cobalt and dysprosium, {[DyCo(oda)(3)](4)[Co (H2O)(6)](2)center dot 6H(2)O)(n) (1) (H(2)oda=oxydiacetic acid), has been synthesized and characterized by X-ray crystal diffraction, magnetic analysis, fluorescence and EPR spectrum as well as TGA studies. The single-crystal analysis shows that compound 1 displays unique hexadecagonal and octagonal channel structure. The photoluminescent spectrum of 1 indicates that the emissions come from intraligand pi-pi* transitions. Temperature-dependent magnetic susceptibilities, EPR and TG properties for 1 also have been discussed.

• 出版日期2011-4
• 单位南开大学; 洛阳师范学院