6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris(thiocyanato-kappa N)cuprate(I)

作者：Xu Na; Niu Yun Yin; Ng Seik Weng^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1280-U1042.

DOI：10.1107/S1600536810036779

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-interacting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 angstrom. The Cu(I) atom is displaced by 0.019 (2) angstrom out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

• 出版日期2010-10
• 单位郑州大学