Application of bisphosphomide-palladium(II) pincer complex in Suzuki-Miyaura cross-coupling reaction under microwave irradiation

作者：Kumaravel Maruthai; Kumar Pawan; Balakrishna Maravanji S^*

来源：Journal of Chemical Sciences, 2014, 126(3): 711-716.

DOI：10.1007/s12039-014-0594-z

• Pincer complex
• bisphosphomide
• Suzuki-Miyaura coupling
• microwave irradiation
• palladium(II)

The bisphosphomide-based pincer complex [PdBr{2,6-{ Ph2PC(O)}(2)(C6H3)}] (2) has shown very high catalytic activity in Suzuki-Miyaura cross coupling reaction under microwave irradiation for a variety of aryl bromides and aryl boronic acids. The complex showed the same efficiency for gram scale reactions.

• 出版日期2014-5