alpha-Fused Dithienyl BODIPYs Synthesized by Oxidative Ring Closure

作者：Heyer Elodie; Retailleau Pascal; Ziessel Raymond^*

来源：Organic Letters, 2014, 16(9): 2330-2333.

DOI：10.1021/ol500572t

Both symmetrical and unsymmetrical alpha-fused dithienyl-BODIPY dyes have been prepared by oxidative ring closure induced by anhydrous FeCl3. Extension of the pi-system in the fused BODIPY leads to a progressive shift to 579 and 665 rim respectively for the absorption wavelength maxima of the mono- and difused dyes relative to the unfused species (lambda(abs) = 502 nm). Linking such dyes to an NIR emitting module provides a panchromatic chromophore with a large absorption cross section in the visible range associated with efficient intramolecular cascade energy transfer.

• 出版日期2014-5-2