A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

作者：Souto Manuel; Santiago Portillo Andrea; Palomino Miguel; Vitorica Yrezabal Inigo J; Vieira Bruno J C; Waerenborgh Joao C; Valencia Susana; Navalon Sergio; Rey Fernando; Garcia Hermenegildo; Minguez Espallargas Guillermo

来源：Chemical Science, 2018, 9(9): 2413-2418.

DOI：10.1039/c7sc04829g

Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe-3(mu(3)-O)( COO)(6)] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

• 出版日期2018-3-7